H2N2V1, Main, Exploration, bibRecord, 001A04

Applications of Nonlinear Observers and Control: Improving Productivity and Control of Free Radical Solution Copolymerization

Identifieur interne : 001A04 ( Main/Exploration ); précédent : 001A03; suivant : 001A05

Applications of Nonlinear Observers and Control: Improving Productivity and Control of Free Radical Solution Copolymerization

Auteurs : H. Hammouri [France] ; T. F. Mckenna [France] ; S. Othman [France]

Source :

Industrial & Engineering Chemistry Research [ 0888-5885 ] ; 1999.

RBID : ISTEX:57200715B7F5D7E5C32C2973FB0D46E9CB7FA99F

Abstract

A nonlinear state observer that uses the rate of heat generation due to chemical reaction for the real-time evaluation of key parameters during free radical solution copolymerization is presented. These parameters include the cumulative and instantaneous copolymer compositions, the overall and individual monomer conversions, and the overall termination rate constant associated with the reaction. The information thus obtained is used to control the cumulative copolymer composition and to maintain the productivity of a semibatch reactor for the solution copolymerization of butyl acrylate (BuA) and vinyl acetate (VAc) in ethyl acetate (EAc) at its highest possible level. Both the state and parameter estimation of this observer were then used for the nonlinear control of copolymer composition and optimal reactor productivity.

Url:

https://api.istex.fr/ark:/67375/TPS-4VBJV86Z-F/fulltext.pdf

DOI: 10.1021/ie9806996

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001472
to stream Istex, to step Curation: 001472
to stream Istex, to step Checkpoint: 000804
to stream Main, to step Merge: 001A51
to stream Main, to step Curation: 001A04

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Applications of Nonlinear Observers and Control:  Improving Productivity and Control of Free Radical Solution Copolymerization</title>
<author><name sortKey="Hammouri, H" sort="Hammouri, H" uniqKey="Hammouri H" first="H." last="Hammouri">H. Hammouri</name>
</author>
<author><name sortKey="Mckenna, T F" sort="Mckenna, T F" uniqKey="Mckenna T" first="T. F." last="Mckenna">T. F. Mckenna</name>
</author>
<author><name sortKey="Othman, S" sort="Othman, S" uniqKey="Othman S" first="S." last="Othman">S. Othman</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:57200715B7F5D7E5C32C2973FB0D46E9CB7FA99F</idno>
<date when="1999" year="1999">1999</date>
<idno type="doi">10.1021/ie9806996</idno>
<idno type="url">https://api.istex.fr/ark:/67375/TPS-4VBJV86Z-F/fulltext.pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001472</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001472</idno>
<idno type="wicri:Area/Istex/Curation">001472</idno>
<idno type="wicri:Area/Istex/Checkpoint">000804</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000804</idno>
<idno type="wicri:doubleKey">0888-5885:1999:Hammouri H:applications:of:nonlinear</idno>
<idno type="wicri:Area/Main/Merge">001A51</idno>
<idno type="wicri:Area/Main/Curation">001A04</idno>
<idno type="wicri:Area/Main/Exploration">001A04</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Applications of Nonlinear Observers and Control:  Improving
Productivity and Control of Free Radical Solution Copolymerization</title>
<author><name sortKey="Hammouri, H" sort="Hammouri, H" uniqKey="Hammouri H" first="H." last="Hammouri">H. Hammouri</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>LAGEP-UPRESA CNRS Q5007/CPE, University Lyon I, 43 Blvd. du 11 Novembre 1918,69622 Villeurbanne Cedex, France, and LCPP-CNRS/CPE, Bât. F308, 43 Blvd. du 11 Novembre 1918,69616 Villeurbanne Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
<affiliation></affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">France</country>
</affiliation>
</author>
<author><name sortKey="Mckenna, T F" sort="Mckenna, T F" uniqKey="Mckenna T" first="T. F." last="Mckenna">T. F. Mckenna</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>LAGEP-UPRESA CNRS Q5007/CPE, University Lyon I, 43 Blvd. du 11 Novembre 1918,69622 Villeurbanne Cedex, France, and LCPP-CNRS/CPE, Bât. F308, 43 Blvd. du 11 Novembre 1918,69616 Villeurbanne Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
<affiliation></affiliation>
</author>
<author><name sortKey="Othman, S" sort="Othman, S" uniqKey="Othman S" first="S." last="Othman">S. Othman</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>LAGEP-UPRESA CNRS Q5007/CPE, University Lyon I, 43 Blvd. du 11 Novembre 1918,69622 Villeurbanne Cedex, France, and LCPP-CNRS/CPE, Bât. F308, 43 Blvd. du 11 Novembre 1918,69616 Villeurbanne Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
<affiliation></affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">Industrial & Engineering Chemistry Research</title>
<title level="j" type="abbrev">Ind. Eng. Chem. Res.</title>
<idno type="ISSN">0888-5885</idno>
<idno type="eISSN">1520-5045</idno>
<imprint><publisher>American Chemical Society</publisher>
<date type="e-published" when="1999-11-05">1999</date>
<date when="1999-12-06">1999</date>
<biblScope unit="vol">38</biblScope>
<biblScope unit="issue">12</biblScope>
<biblScope unit="page" from="4815">4815</biblScope>
<biblScope unit="page" to="4824">4824</biblScope>
</imprint>
<idno type="ISSN">0888-5885</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0888-5885</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract">A nonlinear state observer that uses the rate of heat generation due to chemical reaction for the real-time evaluation of key parameters during free radical solution copolymerization is presented. These parameters include the cumulative and instantaneous copolymer compositions, the overall and individual monomer conversions, and the overall termination rate constant associated with the reaction. The information thus obtained is used to control the cumulative copolymer composition and to maintain the productivity of a semibatch reactor for the solution copolymerization of butyl acrylate (BuA) and vinyl acetate (VAc) in ethyl acetate (EAc) at its highest possible level. Both the state and parameter estimation of this observer were then used for the nonlinear control of copolymer composition and optimal reactor productivity.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
</country>
<region><li>Auvergne-Rhône-Alpes</li>
<li>Rhône-Alpes</li>
</region>
<settlement><li>Villeurbanne</li>
</settlement>
</list>
<tree><country name="France"><region name="Auvergne-Rhône-Alpes"><name sortKey="Hammouri, H" sort="Hammouri, H" uniqKey="Hammouri H" first="H." last="Hammouri">H. Hammouri</name>
</region>
<name sortKey="Hammouri, H" sort="Hammouri, H" uniqKey="Hammouri H" first="H." last="Hammouri">H. Hammouri</name>
<name sortKey="Mckenna, T F" sort="Mckenna, T F" uniqKey="Mckenna T" first="T. F." last="Mckenna">T. F. Mckenna</name>
<name sortKey="Othman, S" sort="Othman, S" uniqKey="Othman S" first="S." last="Othman">S. Othman</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001A04 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001A04 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    H2N2V1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:57200715B7F5D7E5C32C2973FB0D46E9CB7FA99F
   |texte=   Applications of Nonlinear Observers and Control:  Improving Productivity and Control of Free Radical Solution Copolymerization
}}

This area was generated with Dilib version V0.6.33.
Data generation: Tue Apr 14 19:59:40 2020. Site generation: Thu Mar 25 15:38:26 2021

	Serveur d'exploration H2N2
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration H2N2

Applications of Nonlinear Observers and Control: Improving Productivity and Control of Free Radical Solution Copolymerization

Applications of Nonlinear Observers and Control: Improving Productivity and Control of Free Radical Solution Copolymerization

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri